Yes, agree on that if BCCW is mainly soluble iron or other metal waste. However, we are not sure whether the COD is caused by the cleaning chemical or soluble metals.

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Yes, agree on that if BCCW is mainly soluble iron or other metal waste. However, we are not sure whether the COD is caused by the cleaning chemical or soluble metals.

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Ph adjustments with a little polymer will remove most metals. Lab test a small sample of your boiler backwash water using the ph adjustment method (you should observe solids forming when you change the pH of the boiler backwash water) then measure the COD of the boiler water without the solids in it to see how much the COD is reduced. Take a look at the pH of the cleaning/ scale removal chemical to get an idea where to start with adding acid or base.  Keep us posted with the results.   

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