When you add 50 ppm of CO2 and you only need 46.64 ppm, then the difference of 'Free' CO2 equals 50 - 46.64 = 3.36 ppm.

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When you add 50 ppm of CO2 and you only need 46.64 ppm, then the difference of 'Free' CO2 equals 50 - 46.64 = 3.36 ppm.