I am not fully sure where ...

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I am not fully sure where your odor is created but, here is what we do in our collections system to keep odor and corrosion down all the way through the process. We add Neutrac SLS45 (Supplied by Univar) which is a lime slurry product. This adds alkalinity which aids in our treatment all the way through our process.  This product will settle out over time and added maintenance will be required.