Everybody is focusing on ...

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Everybody is focusing on Pipe leaks, but there is no mention of such problem on the text. From the "leak" theorist, I must assume that you are saying that it is INWARDS, creating contamination. I don´t really see how a flow reduction can create a pH change. So let us focus on a non-leaking pipe scenario and provide answers, not comments: What is the pipe material? I am suspecting concrete. The best way is CO2, because in fact you are "eating up" your pipe, something that sounds even more pausible when starting the journey at 7.1 pH. Happened in Ryihad years ago but not a single "gurú" would accept that possibility... until we fixed it. HEY, CO2 is a very misunderstood product. be very suspicious of the "expert" solutions coming from the guys that will sell you gas.

Just to be sure: Are you SURE your alkalinity at entry is good?