How Arabian Sea water may be ...

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How Arabian Sea water may be treated to use as Industrial/domestic purpose?
An expert Prem Baboo replied:
In view of the ​ever-increasing ​threat of ​marine ​pollution along ​Karachi coast ​and its ​possible danger ​to the coastal ​and marine ​environment. ​Although there ​have been a ​number of ​overviews on ​status of ​marine ​pollution in ​Pakistan, to ​quantify the ​level of oil ​pollution in ​the coastal ​environment of ​Karachi, ​Pakistan. Water ​and sediment ​samples were ​collected from ​various ​locations along ​Karachi coast ​bordering ​northern ​Arabian Sea. ​Water quality ​was assessed ​using the ​parameters ​salinity, ​dissolved ​oxygen, ​suspended load, ​organic matter (​in particulate ​carbon) and ​total oil and ​grease. The ​salinity in ​Karachi Harbour ​ranged between ​ 25.062–36.042 ppt in the Down ​Stream Lyari ​River Mouth and ​outside Manora ​Channel to open ​sea respectively.​ The dissolved ​oxygen values ​observed at all ​stations ranged ​between ​ 0–6.01 mg/l . Complete ​anoxic ​condition with ​zero oxygen ​value was found ​at Lyari River ​Mouth the ​discharge point ​of mostly ​untreated ​industrial and ​domestic wastes.​ The very high ​concentrations ​of suspended ​load have been ​found at ​Korangi creek ​and Gizri creek ​Tip which are ​ 177.6 ppm , and 100 ppm respectively. ​Concentrations ​of the ​suspended load ​in Karachi ​Harbour were in ​the range of ​ 28.30–61.60 mg/l however, ​higher values ​have been found ​in the Manora ​Channel and its ​surrounding ​area. The level ​of organic ​matter ranged ​between ​ 2.35–11.50 mg/l, with high ​values detected ​in Korangi ​creek and Gizri ​creek, which ​were 11.5mg/l and 7.15 mg/l respectively. ​The concentration ​of total oil ​and grease in ​seawater was ​detected in the ​range of ​ 0.9–49.9 mg/l . The highest ​concentration ​of total oil ​and grease ​ (49.9 mg/l) in seawater ​had been ​observed in ​Manora Channel. ​Similar results ​were also ​observed for ​total oil and ​grease in ​sediments. The ​highest ​concentration ​in sediment was ​found in Manora ​Channel, and ​Korangi creek ​which were ​ 115 mg/kg, and 81 mg/kg respectively. ​The lowest ​value ​ 0.9 mg/l was detected ​in water sample ​collected out ​side Manora ​Channel in the ​open sea, which ​clearly showed ​that the ​pollution level ​decreased from ​Karachi Harbour ​towards open ​sea, due to ​tidal flushing ​and mixing of ​pollutant with ​seawater. ​Karachi the ​largest ​industrial and ​thickly ​populated city ​of Pakistan ​which is ​situated at the ​north western ​boundary the ​Arabian Sea is ​highly ​vulnerable to ​flood damages ​either due to ​flash floods ​during SW ​monsoon or ​impact of sea ​level rise and ​storm surges ​coupled with ​cyclones ​passing through ​Arabian Sea ​along Pakistan ​Coast.​

Comments From Mr.Anjum Alvi: An Ex Employee of Subject Plant.

To begin ​seawater ​desalination ​water treatment,​ a stable, high ​quality feed ​water is ​required –​ this optimises ​membrane ​durability. ​Depending on ​the water ​purification ​system, from ​here water ​heads either to ​the distillation ​solution or ​membrane ​solution.

What the writer is writing is true for R.O. plants. The coastal sea water along Karachi beach is even worst.

 In the urban belt, even raw sewage is dumped directly into sea as no sewage treatment plant is operational for 14-15 million people. This sea water is NOT suitable for R.O. intake unless extraordinary pre-treatment is designed and installed, raising the capital and production cost. That is why we have seen and know very well that big R.O. plant is not and has never been feasibly successful for Karachi beach water when it is meant for bulk supply to the consumers. Small size R.O. units for bottling mineral water or supplying for any industrial needs may be technically or financially feasible but when comes to plants for supplying in bulk to any community of say ¼ to many million GPD, then none of the desalination plants are profitable. In Europe and Middle East and all over the world it is Government’s responsibility to subsidize the cost and supply Desalinated Water to public where natural streams are in scarcity. That is why there is no Desalinated Plants supplying bulk water to communities in private sector all over the world. In Pakistan, the production cost alone comes out around Rs.650-700 per 1000 gallon which is too much for a consumer to pay. Depending upon the quality of feed water, the capital and production cost of R.O. water may vary further.

For ​distillation ​processes, the ​technology used ​to vaporise ​is ​Multiple Effect ​Distillation(​MED), a low ​temperature sea ​water ​distillation ​process used to ​evaporate ​seawater in ​numerous stages ​– up to ​14 stages in ​some instances ​– at ​temperatures of ​70° C or ​lower to ​produce clean ​distillate ​water. ​

Mr.Anjum Alvi : Replied.

That is why the Cogen Plant was considered and installed with MED unit, which is a hot distillation process. It has a series of evaporation and condensation process and hence does not require very stringent feed water quality. It operates on waste heat available from any source at 65-70 degree C. The Cogen plant gets spared steam from a combined cycle power plant. The MED plant produces distillate and also in return supplies condensate and make up water to the HRSG of power plant to continue its operation. That is the operation of both the plants are dependent to each other, if one is shut down the other will also not work. However, it is a wrong perception that Cogen Plant is shut down due to problem in Desalination /MED Plant. There has NOT been serious issues with the MED Plant. The Plant is shut down due to problems in the main prime mover (GT) of the power plant which has nothing to do with quality of sea water. The plant is still technically doable and can be rehabilitated if some investor comes forward and invest money. However, ever rising liabilities on the company due to long shutdown are getting enormous, that is making the financial model unattainable for getting allowable power tariff from NEPRA.

Make the water ​suitable for ​drinking ​purposes the ​following ​procedures ​should e ​carried out:​

Removal of suspended matter.e
​Decolourisation ​and oxidisation ​of the ​inorganic ​material and ​killing of all ​pathogenic ​micro-organisms ​by adding ​chlorine (pre-​chlorination).​
Aeration of water.
Oil removal by ​gravity settler ​Or disc oil ​system.​
​Flocculation of ​colloidal/​organic matter ​with aluminium ​sulphate and ​anionic ​polyelectrolyte.​
Sedimentation.
Filtering.
Addition of lime. .
Post chlorination

Mr.Anjum Alvi Replied:

In April, 2008 when the plant was commissioned and operating for 9 months there has been some problem in operating MED unit due to excessive silt coming in with the sea water feed. At that time, DHA was dumping thousands of tons of sand/earth every day to reclaim area for the Emaar housing project located next to Cogen. With the result the heavy silt ingress in feed was requiring excessive cleaning and/or replacement of filters. Considering the silting issue as a long term problem for this area, a sedimentation tank at the sea water intake was planned and a model testing was carried out successfully in 2009 in Germany to execute the same. That proposal is still available to resolve the silting issue, if it reappears in future.

If you let me know the intention of your interest in this field, maybe I can assist you further.

Regards.

 

Anjum