Hi Anvar, Petroleum ...
Published by Daniel Couton, Process and Environmental Chemist
Hi Anvar,
Petroleum Products and Dissolved Hydrocarbons - can these 2 terms be taken same. This is to check compliance with WHO
I would say no. Petroleum products covers a very wide range of compounds, both water soluble and insoluble. Dissolved Hydrocarbons would be a subset of Petroleum Products (only those compounds that are water soluble). The 'Guidelines for drinking-water quality: fourth edition incorporating the first
addendum' provides the following comment on Petroleum Products:
So there is no guideline value for Petroleum Products in this reference. I was unable to any reference to Dissolved Hydrocarbons in this document. Could you let me know which reference you obtained the value for Dissolved Hydrocarbons from?
If both are different, then how do we deal with the distillate & hydrocarbons as stated in the rider. Based on the above I think that you could focus on the 'Dissolved Hydrocarbons'. Dissolved Hydrocarbons are likely to be smaller hydrocarbons, including TPH, BTEXN and PAH compounds. The solubility/miscibility of hydrocarbons in water reduces sharply as the number of carbons in the molecule increases.
There is a good paper which shows this:
https://www.nrcresearchpress.com/doi/pdfplus/10.1139/v73-599
I think that if you had process in place to remove bulk organics (Petroleum Products) and possibly a separate removal process specifically to remove Dissolved Hydrocarbons you would meet the WHO requirement.
In addition you should be monitoring your product water for TRH(C1-C10), BTEXN and PAH suites. These are standard analytical suites that most laboratories should provide.
Of course this should be subject to a proper risk assessment (I don't know what the composition of your feed water is or what you plan to do with it).
Are dissolved hydrocarbons, as a parameter more stringent than the WHO defined Petroleum Products
It would seem so. There appears to be no guideline value for Petroleum Products in the ' Guidelines for drinking-water quality: fourth edition incorporating the first addendum'.
While there also appears to be no specific guideline value (that I could find) for Dissolved Hydrocarbons there are guideline values for the various compounds that would make up Dissolved Hydrocarbons.